Hebei Sankai Chemical Technology Co., Ltd

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Hebei Sankai Chemical Technology Co., Ltd
Country:  China (Mainland)
Business Type:  Trading Company
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Mr.shao
Tel: +86 15932099601
Mr.Dylan
Tel: +8619565625236
Ms.Cassie
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Burgess reagent CAS29684-56-8

Burgess reagent CAS29684-56-8 CAS NO.29684-56-8

  • FOB Price: USD: 289.00-499.00 /Kilogram Get Latest Price
  • Min.Order: 1 Kilogram
  • Payment Terms: T/T,MoneyGram,Other
  • Available Specifications:

    一(1-10)Kilogram一(11-100)Kilogram一(101-1000)Kilogram

  • Product Details

Keywords

  • Burgess reagent
  • Ammonium, triethyl[[(hydroxymethoxymethylene)amino]sulfonyl]-, inner salt
  • Chemcial

Quick Details

  • ProName: Burgess reagent CAS29684-56-8
  • CasNo: 29684-56-8
  • Molecular Formula: 29684-56-8
  • Appearance: Slightly yellow powder
  • Application: Burgess reagent is a mild selective de...
  • DeliveryTime: 3-7days
  • PackAge: fiber can
  • Port: Tianjin Xingang/Qingdao Port
  • ProductionCapacity: 100 Metric Ton/Month
  • Purity: 98%
  • Storage: Seal and store in a cool and dry place
  • Transportation: By sea/air/land
  • LimitNum: 1 Kilogram

Superiority

1. Product advantages

♦ High purity, all above 98.5%, no impurities after dissolution

♦ We will test each batch to ensure quality

♦ OEM and private brand services designed for free

♦ Various cap colors available

♦ We can also provide MT1 peptide powder

2. Factory advantages

♦ Professional research team

♦ More than 5 doctors in high-tech R&D laboratories

♦ More than 1000 m2 of factory production line to ensure stable supply

♦ More than 1200 factories to manufacture products and control quality

3. Service advantages

♦ 24-hour online service

♦ Track package information and update it for customers

♦ Professional sales team

♦ Accept small order service

♦ Redelivery service if detained by customs

Details

physical and chemical properties
melting point 76-79 °C(lit.)
molecular formula C8H18N2O4S
molecular weight 238.305
Precise quality 238.098724
PSA 68.82000
LogP 2.32860
Appearance traits Off-white crystals
Storage conditions −20°C
stability

1. Burgess reagent is easy to oxidize, and at the same time it is also very sensitive to moisture, and should be used immediately after fresh preparation.

2. Burgess reagent is a highly efficient dehydrogenation reagent that can be used for the preparation reaction from formamide, nitroalkane compounds to isocyanide, nitrile and oxide nitrile compounds. In recent years, the biggest use of Burgess reagent is to realize the cyclic dehydrogenation reaction of hydroxyamide and sulfamide to obtain the corresponding heterocyclic compound.

The chiral center attached to 2-C in thiazoline is prone to epimerization, so much so that most cyclic dehydrogenation reactions of hydroxysulfamides produce enantiomer mixtures. However, under the induction of Burgess Reagent 1, hydroxysulfamide will obtain chiral monomers with high stereoselectivity of 96% yield and greater than 94% enantioselectivity.

Compared with Burgess Reagent 2 itself, the reagent 1 obtained by ligating Burgess reagent with polyethylene glycol can induce the preparation of zoline and thiazoline compounds at a higher yield.

Induced by dehydrogenation reagent 2, hydroxysulfamide can be converted to thiazide at high yield, which is a higher yield than the Mitusnobu reaction.

Computational Chemistry

1. Reference value (XlogP) for calculating hydrophobic parameters: 2

2. Number of hydrogen bond donors: 0

3. Number of hydrogen bond receptors: 5

4. Number of rotatable chemical bonds: 6

5. Number of tautomers:

6. Topological molecular polar surface area (TPSA): 78.8

7. Number of heavy atoms: 15

8. Surface charge: 0

9. Complexity: 306

10. Number of isotope atoms: 0

11. Determine the number of atomic stereoscopic centers: 0

12. Uncertain number of atomic stereoscopic centers: 0

13. Determine the number of chemical bond stereotactic centers: 1

14. The number of stereotactic centers of uncertain chemical bonds: 0

15. Number of covalent bond units: 1

more

1. Properties: creamy crystalline powder

2. Density (g/mL, 20°C): not determined

3. Relative vapor density (g/mL, air = 1): not determined

4. Melting point (ºC): 76-79

5. Boiling point (ºC, normal pressure): not determined

6. Boiling point (ºC, KPa): not determined

7. Refractive index: not determined

8. Flash point (ºC): Not determined

9. Specific optical rotation (º): not determined

10. Spontaneous ignition point or ignition temperature (ºC): not determined

11. Vapor pressure (Pa, 20ºC): not determined

12. Saturation vapor pressure (KPa, 25ºC): not determined

13. Heat of combustion (KJ/mol): not determined

14. Critical temperature (ºC): not determined

15. Critical Pressure (KPa): Not determined

16. Logarithmic value of oil-water (octanol/water) partition coefficient: not determined

17. Upper limit of explosion (%, V/V): Not determined

18. Lower explosion limit (%, V/V): not determined

19. Solubility: Not determined

 

Package

 

Delivery

Our company has long-term cooperation with many world-famous logistics companies to ensure transportation efficiency and cargo safety.

 

 

 

 

 

By Express

By air

By Sea

Suitable for under 50kg
Fast: 3-7 days
High cost
Door to door service,
easy to pick up the goods

Suitable for more than 50kg
Fast: 3-7 days
High cost
Port to port,
professional broker needed

Suitable for more than 500kg
Slow: 7-45 days
Low cost
Port to port,
professional broker needed

 

FAQ

1. Are you a trade company or factory   
We are a  factory with our own trading company.  

2. How long is lead time  
We deliver goods within 3 days for small order, 7-10 days for bulk order.   

3. Where is your factory located How can I visit the factory   
 Our factory located in WEIFANG, China. It is only two hours from QINGDAO.  

4. Can i get some samples 
  Yes, we can supply free sample, but the shipping cost be paid by our customers. 

5. How to start orders or make payments 
  Proforma invoice will be sent first after confirmation of order, enclosed our bank information.Payment by T/T,  

6. How to confirm the Product Quality before placing orders 
  You can get free samples for some products,you only need to pay the shipping cost or arrange a courier to us and take the samples. 
  You can send us your product specifications and requests,we will manufacture the products according to your requests.

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